Showing posts with label properties. Show all posts
Showing posts with label properties. Show all posts

Monday, 28 September 2009

Suitability of a fiber for a blend



Fibers in a blend are chosen keeping in mind various properties of the constituent fibers. Thus a blend is chosen which gives the best of properties of the different constituents of the blend. The properties that are considered can be strength, absorbency,crease resistance, resistance to abrasion, resistance to heat, bulkiness,resistance to pilling and Dimensional stability.All the fibers do not have all the properties that are desired. This is the very reason why blend is chosen.

Cotton has moderate strength and dimensional stability. However, it is excellent in absorbency, resistance to heat and pilling. It has an average resistance to abrasion and poor bulkiness properties and crease retention.Thus it is added in the blend to have excellent absorbency properties.

Viscose Rayon has excellent absorbency, resistance to heat and pilling. Thus it is similar to cotton in these properties.It has however, poor resistance to abrasion, bulkiness, crease retention and stability. It has an average strength. It has absorbency properties similar to cotton. It is also cheaper than cotton.

Acetate Rayon has excellent resistance to pilling and stability. It has moderate resistance to heat and average absorbency, crease retention and stability. However its resistance to abrasion is very poor.

Wool has excellent absorbency, bulk and wrinkle resistance. However, it has poor stability. It has moderate abrasion and heat resistance. Its crease retention, resistance to pilling and strength can only be considered as average.

Nylon has excellent strength, stability and abrasion resistance. However, It has poor absorbency and bulk. It has moderate crease retention and average resistance to heat and pilling.

Polyester has excellent strength, stability, crease retention and abrasion resistance. However it has poor absorbency, bulkiness properties and resistance to pilling. Its resistance to heat is average.

Acrylic has excellent bulk and stability. It has moderate resistance to heat and average crease retention and strength. Its resistance to abrasion and pilling and absorbency are very poor.It is similar to wool in most of the properties. It is also cheaper than wool.

Modacrylic has excellent stability and bulk properties. However its absorbency, resistance to heat and pilling is very poor. It has average strength, resistance to abrasion and crease retention.

Polypropylene and Polyethylene have excellent stability and strength. They have poor absorbency, bulk and heat resistance. The have average crease resistance and resistance to pilling.

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Friday, 15 May 2009

Properties of Cuprammonium Rayon



Properties of Cuprammonium Rayon

Cuprammonium rayon is a regenerated cellulose fibre known especially for its fine filament structure and soft, silk-like handle. Like viscose rayon, it is made from cellulose, but the method of manufacture gives it certain distinctive characteristics, particularly in fineness, appearance, swelling behaviour, and dye absorption.

The following points summarise the important properties of cuprammonium rayon. Some numerical values and older technical descriptions should be verified from standard textile fibre references before academic citation.

1. Extreme Fineness of Filaments

One of the most important characteristics of cuprammonium rayon is the extreme fineness of its filaments. Filaments as fine as about 1.33 denier have been reported as being regularly produced, whereas viscose rayon has often been described in older textile literature as having a usual denier of around 2.5 denier.

This increased fineness is generally associated with the stretching or drawing applied to the filaments during spinning. Finer filaments give the fibre a softer feel and a more delicate drape.

Needs source verification: The specific denier values of 1.33 for cuprammonium rayon and 2.5 for viscose rayon should be checked against a standard textile fibre textbook or manufacturer data.

2. Soft and Silk-like Handle

Because of its fineness, cuprammonium rayon produces a soft, smooth, and silk-like handle. This makes it suitable for lightweight fabrics where softness, fluid drape, and a refined appearance are desired.

In fabric form, this property can be especially useful for dress materials, linings, saree-like drapable fabrics, scarves, and other products where a soft touch is valued.

3. Similarity to Cotton, but with Greater Swelling

Cuprammonium rayon is a regenerated cellulose fibre and therefore has many properties similar to cotton. However, it differs from cotton in some important structural aspects.

The average degree of polymerisation, often written as DP, is lower than that of cotton. Also, a larger portion of the fibre structure is occupied by amorphous regions. Because of this, cuprammonium rayon swells more readily than cotton.

Technical Note:
In textile science, degree of polymerisation refers to the average length of cellulose polymer chains. A lower DP generally indicates shorter cellulose chains. Amorphous regions are less ordered parts of the fibre structure, and these regions are usually more accessible to water, dyes, and chemicals.

As a result of greater swelling and higher accessibility, chemical reactions may take place faster in rayon than in cotton. This is important in wet processing, dyeing, finishing, and chemical treatment.

4. Behaviour on Burning and Exposure to Sunlight

Like viscose rayon, cuprammonium rayon burns rapidly. Older textile sources state that it chars at around 180°C. It is also reported to be degraded and weakened by exposure to sunlight in the presence of oxygen and moisture.

On ignition, cuprammonium rayon may leave behind ash containing traces of copper, due to the copper-based solvent system used in its manufacture.

Needs source verification: The charring temperature of 180°C and the statement regarding copper-containing ash should be checked from authoritative textile testing or fibre chemistry references.

5. Tensile Strength

The average tensile strength of cuprammonium rayon has been reported as approximately 1.7–2.3 in the dry state and 0.9–2.5 in the wet state.

These values appear to come from older fibre-property references. The unit is not mentioned in the original note and should therefore be verified before use in formal academic writing.

Needs source verification: Confirm the tensile strength values and their units. In textile references, fibre tenacity may be expressed in g/denier, cN/tex, or other units.

6. Elongation at Break

Cuprammonium rayon has been reported to show an elongation at break of about 10–17% in the dry state.

This means that the fibre can stretch to some extent before breaking. In practical fabric behaviour, elongation influences comfort, drape, crease recovery, and handling during processing.

Needs source verification: The stated elongation range should be verified from standard fibre-property tables.

7. Moisture Regain

At 70°F and 65% relative humidity, the moisture content of cuprammonium rayon is reported to be about 11%, similar to viscose rayon.

This relatively high moisture regain contributes to comfort in wear, because regenerated cellulose fibres can absorb moisture better than many synthetic fibres such as polyester or nylon.

Needs source verification: The 11% moisture content figure should be checked against standard textile fibre regain tables.

8. Dye Absorption

Cuprammonium rayon has good dye absorption. Its absorption power for direct dyes has been reported to be greater than that of viscose rayon, resulting in deeper shades under comparable dyeing conditions.

This behaviour can be related to the fibre’s accessible cellulose structure and swelling tendency. In practical dyeing, this may affect shade depth, dye uptake, and process control.

Needs source verification: The comparison of direct dye absorption between cuprammonium rayon and viscose rayon should be checked from dyeing or fibre chemistry references.

9. Microscopic Appearance

Under microscopic examination, cuprammonium rayon filaments appear uniform in longitudinal view. Their surfaces generally show no prominent markings.

In cross-section, the filaments are usually round and smooth, though they may occasionally appear slightly oval.

Practical Note:
Microscopic appearance is useful in fibre identification. Cotton shows natural twists or convolutions, while viscose rayon often shows striations. Cuprammonium rayon is generally smoother and more uniform in appearance.

Summary Table: Key Properties of Cuprammonium Rayon

Property Description Practical Significance
Fineness Very fine filaments; older sources mention about 1.33 denier Soft handle, smooth surface, good drape
Handle Soft and silk-like Useful for lightweight, elegant fabrics
Structure Lower DP than cotton; more amorphous regions Greater swelling and chemical accessibility
Burning behaviour Burns rapidly like viscose rayon Important for fibre identification and safety understanding
Strength Moderate tensile strength; reported values need unit verification Affects processing and fabric durability
Elongation About 10–17% dry elongation reported Influences flexibility and fabric behaviour
Moisture content About 11% at 70°F and 65% RH reported Contributes to comfort and absorbency
Dye absorption Good absorption of direct dyes; deeper shades reported than viscose rayon Relevant for dyeing depth and shade control
Microscopic appearance Smooth longitudinal view; round or slightly oval cross-section Useful for fibre identification

Conclusion

Cuprammonium rayon is valued mainly for its fine filament structure, soft silk-like handle, good moisture absorption, and attractive dyeing behaviour. Although it shares many properties with cotton and viscose rayon because all are cellulose-based fibres, its greater fineness and smoother microscopic appearance give it a distinctive character.

For students and textile professionals, cuprammonium rayon is a useful example of how manufacturing method, fibre structure, and end-use performance are closely connected. However, some numerical values commonly found in older notes should be verified from reliable textile references before being used in academic or technical documentation.

Suggested References / Sources to Check

The following references may be useful:

  1. Textile Fibres: Their Physical, Microscopical and Chemical Properties — J. Merritt Matthews
  2. Textile Fibers, Dyes, Finishes, and Processes — Howard L. Needles
  3. Physical Properties of Textile Fibres — W. E. Morton and J. W. S. Hearle
  4. Manufactured Fibre Technology — V. B. Gupta and V. K. Kothari
  5. Identification of Textile Materials — The Textile Institute
  6. Textile Science — E. P. G. Gohl and L. D. Vilensky
  7. Handbook of Textile Fibres: Man-Made Fibres — J. Gordon Cook
  8. BIS, ASTM, or Textile Institute standards on fibre identification and moisture regain
  9. Manufacturer technical data sheets for cupro / cuprammonium rayon
  10. Academic papers or technical notes on regenerated cellulose fibres and cupro fibre properties

Wednesday, 13 May 2009

Properties of Viscose Rayon



Properties of Viscose Rayon

Moisture Absorption

It absorbs more moisture than cotton. Moisture Content of Coton is 6% at 70 deg F and 65% RH, and for Viscose Rayon it is 13% under the same conditions.

Tensile Strength

The Tensile Strength of the fibre is less when the fibre is wet than when dry. It is 1.5-2.4 gpd in the dry state and 0.7-1.2 gpd in the wet state. For high tenacity variety the values are 3-4.6 gpd and 1.9 to 3.0 gpd.

Elasticity

The elasticity of Viscose Rayon is less than 2-3%. This is very important in handling viscose yarns during weaving, stentering etc when sudden tensions are applied.

Elongation at Break

Ordinary Viscose rayon has 15-30% elongation at break, whule high tenacity rayon has only 9-17% elongation at break.

Density

The density of Viscose rayon is 1.53 g/cc. Rayon filaments are available in three densities: 1.5, 3.0 and 4.5

Action of Heat and Light

At 300 deg F or more, VR loses its strength and begins to decompose at 350-400 deg F. Prolonged exposure to sunlight also weakens the fibre due to moisture and ultraviolet light of the sunlight.

Chemical Properties

Viscose rayon consists of cellulose of lower DP than cotton cellulose. Also amorphous region of Viscose rayon is present to a greater extent, therefore, Viscose rayon reacts faster than cotton with chemicals. Acids like H2SO4 HCL breaks the cellulose to hydrocellulose. Oxidising agents like Na(OCl)2, Bleaching powder, K2Cr2O7, KMnO4- form oxycellulose. Cold acid solutions for a short time do not attack viscose rayon.

Action of Solvents

Textile solvents can be used on Viscose rayon without any deteriorating effect. Viscose rayon dissolves in cuprammonium hydroxide solution.

Effect of Iron

Contact with iron in the form of ferrous hydroxide weakens viscose rayon yarns. Therefore staining, marking or touching of rayon to iron or iron surface should be avoided.

Action of Microorganisms

Microorganisms ( moulds, mildew, fungus, bacteria) affect the colour, strength, dyeing properties and lustre of rayon. Clean and dry viscose rayon is rarely attacked by moulds and mildew.

Longitudinal View

The longitudinal view of these fibres show many striations running parallel to the long axis of the fibre. The cross section of viscose has striated periphery, having many sharp indentations, and cross sectional contours vary from circular and oval to ribbon-like forms.

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