Showing posts with label denim dyeing. Show all posts
Showing posts with label denim dyeing. Show all posts

Sunday, 31 May 2026

Controlling Centre-to-Selvedge Colour Variation in Sheet Dyeing of Denim



Controlling Centre-to-Selvedge Colour Variation in Sheet Dyeing of Denim

In denim manufacturing, colour variation is one of the most visible and commercially sensitive problems. A small shade difference that may look harmless on dyed yarn can become very obvious after weaving, garment washing and finishing.

Among the different types of shade variation, one important problem in sheet dyeing or slasher dyeing is centre-to-selvedge colour variation. This happens when the yarns in the centre of the warp sheet dye slightly differently from the yarns near the two selvedges.

After weaving, this may show as darker or lighter bands running lengthwise in the denim fabric. In garment form, it may further become visible as panel-to-panel shade difference, side shading, streakiness or inconsistent washing response.

The problem is not caused by one factor alone. In sheet dyeing, centre-to-selvedge variation is usually born at the intersection of three controls: liquor pick-up, warp-sheet mechanics and indigo bath chemistry.

Central idea: In sheet dyeing, shade is not controlled only by the dye recipe. Shade is controlled by the complete process — yarn preparation, liquor pick-up, nip pressure, tension, oxidation, washing and monitoring.

Table of Contents

  1. What is centre-to-selvedge colour variation?
  2. Why sheet dyeing is sensitive to this problem
  3. Main causes of centre-to-selvedge shade variation
  4. How to control centre-to-selvedge variation
  5. Practical troubleshooting table
  6. A practical control plan for mills
  7. Conclusion
  8. General disclaimer

What is centre-to-selvedge colour variation?

In sheet dyeing, warp yarns are spread side-by-side in open sheet form and pass through dye boxes, squeeze rollers, oxidation zones and sizing units. Ideally, every yarn from the left selvedge to the right selvedge should receive the same dyeing treatment.

In practice, the centre yarns and edge yarns may not behave exactly alike. Centre-to-selvedge variation means that the yarns near the centre of the sheet show a different depth, tone or brightness compared with the yarns near the selvedges.

The difference may be visible immediately after dyeing, but sometimes it becomes clearer only after weaving, finishing or garment washing. This is especially important in denim because washing partly removes and modifies the indigo surface, making earlier shade differences more visible.

Denim is a highly visual fabric. The indigo shade is not only a colour; it is part of the identity of the fabric. Buyers expect a controlled blue, black, grey, sulphur-bottom or topping shade. Any side-to-side difference reduces the acceptability of the fabric.

Why sheet dyeing is sensitive to this problem

In rope dyeing, warp yarns are gathered into ropes, dyed, oxidised and later opened during long-chain beaming. Because the yarns are rearranged during subsequent processing, some shade variation may get distributed.

In sheet dyeing, however, yarns remain in sheet form. The position of the yarn across the width is more directly related to its final position in the fabric. This makes sheet dyeing efficient and compact, but it also makes it more sensitive to width-wise variation.

If the left edge, centre and right edge do not receive the same liquor pick-up, pressure, tension, immersion or oxidation, the variation can directly appear in the woven denim. In simple words, sheet dyeing gives less room to hide width-wise mistakes.

Main causes of centre-to-selvedge shade variation

1. Uneven nip pressure across the width

The padding or squeezing system is one of the most important areas to examine. When yarns come out of the dye box, the squeeze rollers control how much dye liquor remains on the yarn. If nip pressure is not uniform across the full width, liquor pick-up will also not be uniform.

If the centre pressure is higher, the centre yarns may carry less liquor. If the edge pressure is higher, the selvedge yarns may carry less liquor. In both cases, the shade can change across the width.

This may happen because of roller deflection, roller hardness variation, poor roller grinding, incorrect loading, worn bearings, improper alignment or uneven pneumatic or hydraulic pressure. The problem may become more serious on wider machines because roller deflection becomes more difficult to control.

The first rule of centre-to-selvedge control is therefore simple: do not blame the dye before checking the padder or squeeze roller.

2. Variation in liquor pick-up

In indigo sheet dyeing, liquor pick-up determines how much reduced indigo solution is carried by the yarn before oxidation. Any variation in pick-up becomes a variation in available dye.

Liquor pick-up can vary due to nip pressure, yarn absorbency, yarn tension, bath level, viscosity, wetting, foam, contamination or uneven yarn sheet density. Even if the dye bath recipe is correct, poor pick-up control can still produce shade variation.

Liquor pick-up may be expressed as:

\[ \text{Liquor Pick-up \%} = \frac{\text{Wet Weight} - \text{Dry Weight}}{\text{Dry Weight}} \times 100 \]

A practical mill should not depend only on visual judgement. Width-wise pick-up should be checked at the left selvedge, left-middle, centre, right-middle and right selvedge. If the values are not consistent, shade variation is almost expected.

3. Uneven warp tension across the sheet

Warp-sheet tension is another major factor. If some sections of the sheet are tighter than others, the yarns may pass through the bath, squeeze rollers and oxidation zone differently.

Higher tension may flatten the yarn, reduce penetration, alter squeeze-out and change the way the yarn opens during oxidation. Lower tension may allow the yarn to carry more liquor or behave differently at the nip.

Uneven tension can also create small differences in yarn path, contact angle and residence time. Centre-to-selvedge variation should therefore be investigated together with tension variation.

The sheet should enter the dye box evenly and should not show slack edges, tight centre, uneven spreading, crowding or bowing.

4. Uneven wetting and pre-treatment

Before indigo dyeing, cotton warp yarn must be properly prepared. Cotton contains natural waxes, pectins, oils, size residues and other impurities. If these are not removed uniformly, the yarn will not absorb dye liquor uniformly.

Poor wetting is especially dangerous in sheet dyeing. If the centre yarns wet more slowly than the selvedge yarns, or if the selvedge yarns contain more residual wax or size, the dye uptake will differ.

Trapped air in yarns can also reduce liquor contact and create uneven dyeing. Good pre-scouring, wetting-agent control, washing and yarn absorbency testing are therefore essential.

In many mills, the dyeing department tries to correct shade variation that actually started in preparation.

5. Indigo bath instability

Indigo is not applied like many other dyes. It must first be reduced into a soluble leuco form so that it can enter or deposit on the cotton yarn. After dipping, the yarn is exposed to air, where the reduced indigo oxidises back to its insoluble blue form.

Because of this chemistry, the final shade is affected by several variables: indigo concentration, caustic level, reducing-agent level, pH, oxidation-reduction potential, temperature, immersion time, number of dips, oxidation time and wetting agent.

If the bath is unstable, the shade may vary over time. But if bath circulation is poor across the width, or if chemical distribution is not uniform, width-wise variation can also appear.

In a good denim range, indigo bath control should not be based only on recipe addition. The mill should monitor pH, redox condition, temperature, circulation, bath level and concentration at regular intervals.

6. Non-uniform oxidation or skying

After each dip, indigo needs controlled oxidation. Oxidation develops the blue colour and influences brightness, tone and fastness. If oxidation is incomplete or uneven, the shade will vary.

In sheet dyeing, the centre and edge portions of the sheet must receive similar exposure to air. Variation in airflow, sheet spreading, roller path, moisture level or dwell time can create width-wise differences.

If the centre portion remains wetter or less exposed, oxidation may be different from the selvedge portions. Indigo dyeing is not only a dipping process; it is a repeated dip-and-oxidise process.

7. Edge effects and selvedge behaviour

The selvedge side of the warp sheet often behaves differently from the centre. Edge yarns may experience different airflow, drying, tension, guiding pressure or contact with machine elements.

They may also be more exposed to side evaporation, splash, dripping or mechanical disturbance. In some cases, the selvedge becomes lighter because it carries less liquor or oxidises differently.

In other cases, it becomes darker because of higher liquor retention or local accumulation. The exact direction of shade difference depends on the process condition.

Therefore, the question should not be only “Why is the selvedge lighter?” or “Why is the centre darker?” The better question is: Which width-wise process variable is different at that position?

How to control centre-to-selvedge variation

1. Start with width-wise measurement

The first correction is measurement. The mill should build a habit of checking left, centre and right positions. Ideally, five positions should be used: left selvedge, left-middle, centre, right-middle and right selvedge.

At each position, the mill can check shade, liquor pick-up, pH, moisture, tension and yarn appearance. For shade, visual assessment should be supported by spectrophotometer readings wherever possible.

A small colour difference may become commercially significant after garment washing. The colour difference can be expressed using \(\Delta E\), where:

\[ \Delta E = \sqrt{(\Delta L^*)^2 + (\Delta a^*)^2 + (\Delta b^*)^2} \]

Here, \(L^*\) represents lightness, \(a^*\) represents the red-green axis and \(b^*\) represents the yellow-blue axis. Without width-wise data, the discussion remains subjective.

2. Check padder and squeeze roller condition

The padder or squeeze roller system should be checked for uniformity across the width. Important checks include roller hardness, roller surface condition, roller grinding accuracy, nip impression, pressure balance, loading system, bearing condition and roller parallelism.

A simple carbon paper or nip impression test can sometimes reveal what the eye cannot see during running. If the nip is not uniform, the shade cannot be expected to remain uniform.

For wider machines, deflection-controlled or specially designed padders are especially useful because normal rollers may bend under pressure, creating different squeezing behaviour at the centre and edges.

3. Standardise liquor pick-up

Liquor pick-up should be treated as a critical process parameter. It should be measured and recorded, not assumed. If the target pick-up is 70%, the left, centre and right should not show large deviations.

Pick-up control depends on nip pressure, machine speed, yarn absorbency, bath temperature, wetting-agent level, yarn tension, bath level and roller condition. Whenever centre-to-selvedge variation is noticed, pick-up testing should be one of the first diagnostic steps.

4. Maintain uniform warp-sheet tension

The warp sheet should run flat, straight and evenly spread. The machine operator should check whether the sheet is tighter at the centre, looser at the edges, or unstable during running.

Important controls include uniform let-off tension, correct guiding, proper sheet spreading, avoidance of slack selvedges, equal loading across beams, proper alignment of guide rollers and avoidance of yarn crowding or overlapping.

If the sheet itself is mechanically unstable, dyeing uniformity becomes difficult.

5. Improve pre-treatment and wetting

Before dyeing, the yarn should be uniformly absorbent. A simple drop test or absorbency test across width can reveal whether the preparation is consistent.

Good preparation includes removal of wax and impurities, removal or control of previous sizing materials, proper wetting, control of water hardness, effective washing, avoidance of oil or grease contamination and prevention of trapped air.

If yarns do not wet evenly, they cannot dye evenly.

6. Control indigo bath chemistry

The indigo bath should be controlled for concentration, pH, caustic, reducing agent, redox potential, temperature and bath circulation. Operators should avoid large corrections made only after shade variation becomes visible.

A stable bath gives the process a stable base. But stability should mean both length-wise and width-wise stability. The bath should be well circulated, and chemical additions should be properly mixed before they affect the yarn sheet.

Important controls include regular pH checking, ORP monitoring, indigo concentration control, hydrosulphite or reducing-agent control, caustic control, temperature control, foam control, bath level control, filtration and circulation.

7. Ensure uniform oxidation

Oxidation should be uniform across the full sheet width. The yarns should not be crowded, stuck together or unevenly spread during skying. Air movement should not favour one side of the sheet.

Important checks include adequate skying length, uniform airflow, proper yarn separation, consistent machine speed, avoidance of wet patches, no side dripping and stable roller path.

The shade after indigo dyeing is not created inside the dye box alone. It is created by repeated dipping and oxidation. If oxidation is uneven, the shade will also be uneven.

8. Use left-centre-right shade control after washing

Indigo shade should be assessed after proper washing and drying, not only in the wet state. Wet yarns and wet fabric can mislead the eye.

A proper comparison should be done under standard light conditions after the sample reaches a stable state. For better control, mills may maintain a record of left-centre-right shade reading, \(\Delta E\), K/S value, pick-up percentage, bath pH, ORP value, machine speed, nip pressure, oxidation length, lot number and beam number.

Practical troubleshooting table

Observed problem Possible cause What to check first Corrective action
Centre darker than selvedge Higher pick-up at centre or lower squeeze pressure at centre Nip impression and pick-up test Correct roller pressure, alignment or deflection
Selvedge darker than centre Higher pick-up at edges or edge liquor accumulation Edge yarn wetness and squeeze condition Check edge pressure, dripping and guiding
One side darker than the other Left-right pressure imbalance or poor machine alignment Left vs right nip and tension Balance pressure and align rollers
Shade changes after every few hundred metres Bath instability or poor chemical dosing pH, ORP, indigo concentration Stabilise dosing and circulation
Variation increases after washing Uneven ring dyeing or oxidation Oxidation and washing uniformity Improve skying and washing control
Random bands across width Yarn preparation or absorbency variation Width-wise absorbency test Improve scouring and wetting
Thick counts show more variation Poor penetration and higher sensitivity to tension or pick-up Count-wise process settings Adjust dip time, wetting, pressure and speed

A practical control plan for mills

A mill can control centre-to-selvedge variation through a simple but disciplined routine. First, check the machine. The padder, squeeze rollers, guide rollers and tension system should be mechanically sound.

Second, check the yarn sheet. The sheet should run evenly from left to right. There should be no crowding, slack edges, tight centre, broken yarn disturbance or uneven spreading.

Third, check liquor pick-up. Measure it across the width. Do not assume that the centre and selvedge are carrying the same amount of dye liquor.

Fourth, check bath chemistry. Maintain pH, reducing condition, temperature, dye concentration and circulation within the required range.

Fifth, check oxidation. Ensure that the yarn sheet gets uniform exposure to air after every dip.

Sixth, check shade with data. Use left-centre-right readings, \(\Delta E\), K/S values and proper production records.

References and Further Reading

  1. Xin, J. H., Chong, C. L., & Tu, T. M. (2000). Colour variation in the dyeing of denim yarn with indigo. Coloration Technology, 116, 260–265. View source
  2. Cotton Incorporated. Open Width Pad-Batch Dyeing of Cotton Fabrics, Technical Bulletin TRI 3007. View source
  3. EFI Mezzera. Indigo Dyeing and Finishing Ranges / Denim Line Brochure. View source
  4. Textile Commissioner, Government of India. Semi-continuous Openwidth Dyeing Machines. View source
  5. Paul, R. (Ed.). (2015). Denim: Manufacture, Finishing and Applications. Woodhead Publishing / Elsevier. View source

Conclusion

Centre-to-selvedge colour variation in denim sheet dyeing is not a mysterious defect. It is usually the visible result of invisible process differences across the width of the warp sheet.

The most important causes are uneven nip pressure, unequal liquor pick-up, non-uniform tension, poor wetting, unstable indigo chemistry and uneven oxidation. Among these, nip pressure and liquor pick-up deserve special attention because they directly decide how much dye liquor each yarn carries.

In sheet dyeing, the yarns remain spread in open-width form. This gives the process speed, compactness and flexibility, but it also makes width-wise control critical. A well-controlled sheet dyeing range must therefore be managed not only from lot to lot, but also from selvedge to centre to selvedge.

The best approach is not to correct shade variation after it appears, but to prevent it through systematic control of machine condition, yarn preparation, bath chemistry, oxidation and left-centre-right monitoring. In denim, shade is not only a recipe. Shade is a result of the whole process.

General Disclaimer

This article is for educational and general textile knowledge purposes only. Actual denim dyeing results depend on yarn quality, cotton fibre properties, machine design, indigo chemistry, reducing system, process route, water quality, operator skill, maintenance condition, testing method and buyer requirements.

Mills should validate all process changes through laboratory trials, pilot runs and controlled bulk trials before implementing them in commercial production. The author does not accept responsibility for production losses, shade rejections or process failures arising from direct application of this educational material without mill-specific technical verification.

Buy my books at Amazon.com

Thursday, 8 April 2010

Principle of Soft Flow Dyeing Machine



Textile material can be dyed using batch, continuous or semi continuous process.

Batch processes are the most common method used to dye textile materials. There are three general types of batch dyeing machines:
  1. In which fabric is circulated
  2. In which dye bath is circulated
  3.  In which both the bath and material is circulated.
Jet dyeing is the best example of a machine that circulated both the fabric and the dyebath. Jet dyeing is used for knitted fabrics. For Terry-towels soft flow dyeing is use.

In jet dyeing machine the fabric is transported by a high speed jet of dye liquid.

As seen in the figure, this pressure is created by venturi. A powerful pump circulates the dyed bath through a heat exchanger and the cloth chamber. Cloth guide tube helps in circulation of fabric.



The vigorous agitation of fabric and dye formulation in the cloth increases the dyeing rate and uniformity. It minimizes creasing as the fabric is not held in any one configuration for very long.  The lower liquor ration allows shorter dye cycles and saves chemicals and energy.

In soft flow dyeing machines the fabric is transported by a stream of dye liquor. However, the transport is 
assisted by a driven lifter reel.

These machines use a jet having lower velocity that that used on conventional jet dyeing machines.

The soft flow machines are more gentle on the fabric than conventional jet machines.

The following are the features of a soft flow U-Type dyeing machine offered by Taxfab:

1. Machine pressure vessel and major wet parts made of stainless steel AISI 316/ 316 L, highly corrosion resistance material.

2. Heavy duty stainless steel centrifugal pump for optional dye liquor circulation. Highly efficient heat exchanger for fast heating and cooling. 

3.  A stainless steel filtering device placed in such a way for easy cleaning. 

4.   A unique design of jet nozzle can provide high discharge of liquore with subsequent pressure to ensure fast movement of fabric transport upto 300 Mtrs / Min., and the speed of fabric can be adjusted, required to desire quality. 

5. A mirror polished fabric transport perforated basket for easy trouble free movement of fabric from back to the front of machine, perforated basket fabricated in such a way that welding part does not come in contact with fabric.

6. For preparing chemical, colour kitchen tank is provided made out of stainless steel 316, with required valves for auto dozing. 

7. All valves is made of investment casting and is of stainless steel 3l6.

8.Electrical control panel with microprocessor to operate the machine is provided with pneumatic control circuits.

9. Magnetic level indicator duly calibrated for correct liquor measurement. 

10.       Take off reel with direct couple geared motor and stainless steel structure 

11. All safety device required for a pressure vessel is incorporated with the machine.

A front view and side of the machine offered by them is as given below:





Now that you've finished reading this post, what are you going do? You should go join the Forum.

Monday, 15 February 2010

Is Indigo Natural or Synthetic !! How was it manufactured earlier



Is Indigo Natural or Synthetic? How Was Indigo Produced?

The answer to the first part of the question is simple: both. Indigo began its textile journey as a natural dye obtained from plants. Later, with the development of modern chemistry, the same blue colouring substance began to be manufactured synthetically.

Today, most of the indigo used in the textile industry, especially in denim, is synthetic. But historically and culturally, indigo is deeply associated with natural dyeing traditions of India, China and many other parts of the world.

Indigo belongs to the category of water-insoluble dyes. More specifically, it is a vat dye. This means that indigo, in its blue form, does not dissolve in water and cannot be applied to fabric directly like many other dyes. It has to be chemically converted into a soluble form before dyeing, and then converted back into the blue insoluble form on the fibre.

Table of Contents

Indigo in History

Indigo is one of the oldest dyes known to human civilization. It is believed to have been used for dyeing in India and China from very early times, possibly as far back as 2000 BC. The name “indigo” itself is connected with India. The Greeks and Romans referred to it as a blue dye coming from India, often described as “Indian blue.”

Originally, indigo was obtained from plants, especially from species such as Indigofera tinctoria. The leaves of the plant contained the precursor of the dye, but not the ready-made blue dye in a simple usable form. The blue colour had to be developed through fermentation, reduction and oxidation.

This is what makes indigo so fascinating. It is not merely a colouring matter extracted like juice from a plant. It is a dye that requires chemical transformation before it becomes useful.

Chemical Structure of Indigo

The main colouring compound in indigo is called indigotin. Its molecular formula is:

\[ C_{16}H_{10}N_2O_2 \]

The structure of indigo consists of two indole-like units joined together through a central double bond. It also contains two carbonyl groups \((C=O)\) and two nitrogen atoms. A simplified way to understand the molecule is:

\[ \text{Two indole-type units} + \text{central double bond} + \text{two carbonyl groups} \]

The indigo molecule is highly conjugated. This means that electrons are spread over a large part of the molecule. This extended conjugation is responsible for the absorption of visible light and the characteristic deep blue colour of indigo.

Chemical structure of indigo molecule showing two indole units, carbonyl groups and central double bond

Visual 1: Chemical structure of indigo, \(C_{16}H_{10}N_2O_2\).

This structure also explains why indigo is stable and water-insoluble. For dyeing, the molecule has to be temporarily converted into another form.

How Natural Indigo Was Produced

Natural indigo was traditionally obtained from the leaves and stems of indigo plants. The harvested plant material was placed in a vat filled with water. In older traditional processes, urine or other alkaline fermenting materials could also be used. Fermentation was then allowed to take place.

Inside the plant, the main precursor of indigo is indican, a colourless glucoside. During fermentation, indican breaks down into indoxyl and glucose.

Hydrolysis of indican:

\[ \text{Indican} + H_2O \rightarrow \text{Indoxyl} + \text{Glucose} \]

This step is important because the plant does not directly give a strong blue dye. It first gives indoxyl, which is the immediate precursor of indigo. When the fermented liquid is stirred or beaten with poles, oxygen from the air enters the liquid. This oxygen oxidises indoxyl into indigo.

Oxidation of indoxyl:

\[ 2\,\text{Indoxyl} + O_2 \rightarrow \text{Indigo} + 2H_2O \]

As indigo is insoluble in water, the blue particles begin to separate out and settle at the bottom of the vat. The liquid above is drained off, and the remaining blue sludge or mash is collected. This mash is then dried in the open air and sold in the form of pressed cakes, lumps or powder.

This traditional method explains why indigo production was both an agricultural activity and a chemical process. The farmer grew the plant, but the dyer or processor had to understand fermentation, aeration, settling and drying.

Flow chart showing natural indigo production from plant leaves to fermentation, oxidation, precipitation and drying
Visual 2: Natural indigo production from leaves to indigo cake or powder.

Indigo as a Vat Dye

Indigo is insoluble in its blue form. Therefore, to dye fabric with indigo, it must first be reduced into a soluble form called leuco-indigo. This reduced form is pale yellowish or greenish and can dissolve in an alkaline dye bath.

Reduction of indigo:

\[ \text{Indigo} + 2e^- + 2H^+ \rightarrow \text{Leuco-indigo} \]

In this reduced form, indigo can enter or deposit onto the fibre. When the yarn or fabric is removed from the dye bath and exposed to air, oxygen converts leuco-indigo back into blue indigo.

Oxidation after dyeing:

\[ \text{Leuco-indigo} + \frac{1}{2}O_2 \rightarrow \text{Indigo} + H_2O \]

This is the magical moment in indigo dyeing. The material may come out of the vat looking yellowish-green, but slowly turns blue as it reacts with oxygen in the air.

Practical textile point: This conversion from insoluble blue indigo to soluble leuco-indigo, and then back to insoluble blue indigo, is the heart of vat dyeing.


Indigo vat dyeing cycle showing reduction to leuco-indigo, dyeing, oxidation and blue colour development
Visual 3: Indigo vat dyeing cycle: reduction, dyeing and oxidation.

Why Stirring Was Important

In traditional indigo production, the fermented mass was stirred or beaten with poles. This was not merely a mechanical operation. It had a chemical purpose.

During fermentation, the precursor compounds were converted into reduced or reactive forms. When the liquid was stirred, air entered the vat. The oxygen in the air converted indoxyl into indigo. Since indigo is insoluble, it appeared as blue particles and settled at the bottom.

\[ \text{Fermentation develops the precursor} \]

\[ \text{Stirring introduces oxygen} \]

\[ \text{Oxygen converts the precursor into blue indigo} \]

\[ \text{Insoluble indigo settles at the bottom} \]

This is why the process required both patience and skill. Too little fermentation, too much fermentation, insufficient aeration or poor settling could all affect the quality of the final dye.

From Natural Indigo to Synthetic Indigo

Thus, indigo began as a natural dye. For centuries, India was one of the important sources of natural indigo. Indigo was exported as a valuable dye material, and the term “Indian blue” became associated with it.

However, in the nineteenth century, European chemists began studying the structure and synthesis of indigo. Adolf von Baeyer made major contributions to the chemistry of indigo and succeeded in synthesising it in the laboratory. Later, in 1897, BASF began industrial-scale production of synthetic indigo.

This changed the dye industry completely. Synthetic indigo gave manufacturers a more consistent, predictable and scalable source of blue dye. Natural indigo depended on crop quality, climate, fermentation conditions and extraction skill. Synthetic indigo could be produced in large quantities with more uniform strength and shade.

Over time, synthetic indigo almost completely replaced natural indigo in large-scale textile production.

Natural Indigo vs Synthetic Indigo

Point Natural Indigo Synthetic Indigo
Source Plant-based, mainly from indigo-bearing plants such as Indigofera tinctoria. Manufactured chemically.
Main colouring compound Indigotin. Indigotin.
Molecular formula \(C_{16}H_{10}N_2O_2\) \(C_{16}H_{10}N_2O_2\)
Consistency May vary from batch to batch. More uniform and predictable.
Scale Suitable for craft, heritage and natural dyeing. Suitable for industrial denim production.
Process control Depends on fermentation and extraction. Depends on chemical manufacturing controls.
Present use Niche use in natural dyeing, handcraft and sustainable fashion. Dominant in denim and industrial textile dyeing.

The important point is that the main blue molecule is the same: indigotin. The difference lies mainly in the source, impurities, production method, consistency and environmental profile.

Indigo and Denim

Today, indigo is most strongly associated with denim. Cotton warp yarns are dyed with indigo, while the weft often remains undyed or lightly coloured. In denim dyeing, yarns are repeatedly dipped into the reduced indigo bath and then exposed to air for oxidation.

This repeated dipping and oxidation builds up the blue shade gradually. One interesting property of indigo dyeing is that the dye often remains more concentrated near the surface of the yarn rather than penetrating fully into the core. This is one reason denim fades beautifully with wear.

As the outer surface of the yarn is abraded, some of the indigo is removed, revealing lighter areas. This gives denim its characteristic worn, faded and aged appearance. So, in denim, fading is not always a defect. It is often part of the desired aesthetic.

A Small Correction to Understand the Old Process Better

In older descriptions, it is sometimes said that hydrogen was created by microorganisms and acted as a reducing agent. This is a simplified way of explaining the process. More accurately, fermentation creates reducing conditions in the vat. These reducing conditions help convert dye precursors into forms that can later be oxidised into indigo.

Similarly, when the liquid is stirred, the aim is to introduce oxygen. Oxygen converts the soluble or reduced precursor into insoluble blue indigo. The blue particles then settle at the bottom.

\[ \text{Reduction during fermentation} \]

\[ \text{Oxidation during beating or aeration} \]

This reduction-oxidation cycle is also central to indigo dyeing on fabric.

Conclusion

Indigo is both natural and synthetic. Historically, it was obtained from plants and processed through fermentation, aeration, settling and drying. Later, chemists discovered how to produce the same blue colouring substance synthetically. With industrial production by BASF in the late nineteenth century, synthetic indigo gradually replaced natural indigo in most commercial textile applications.

The beauty of indigo lies in its chemistry. It is a water-insoluble vat dye. It must first be reduced to a soluble leuco form, then applied to the fibre, and finally oxidised back to the blue insoluble form.

This is why indigo is not just a dye. It is a story of plants, fermentation, chemistry, trade, denim and textile technology.

General Disclaimer

This article is intended for educational and general textile knowledge purposes only. The chemical reactions shown are simplified to explain the main principles of natural indigo formation and vat dyeing. Actual indigo extraction, dye reduction, denim dyeing, effluent treatment and chemical handling require proper technical knowledge, safety precautions, process control and laboratory or mill-level validation.

Saturday, 25 April 2009

Controlling Shade in Indigo Dyeing of Denim



If shade is getting:

Redder- Increase the conc. of Caustic , slightly decrease the conc. of Hydro
Redder, Duller- Increase the con. of hydro
Greener, Paler- decrease the con. of hydro
Greener, duller- Increase the con. of caustic
Bronzing- Increasing the con. of Hydro

Monday, 16 March 2009

Receipes for different shades of Denim



Receipes For Different Shades on Denim


A) Black-on-Black
Black-on-Blue


Recipe

Liquid Sulphast Black= 200 gpl
Sodium Sulphide= 20 gpl
Sandozol HSI = 10 gpl
Soda Ash= 10 gpl

B) Blue-on- Blue

Receipe

Liquid Sulphar Navy Blue = 100 gpl
Liquid Sulphast Black= 50 gpl
Sodium Sulphide= 20 gpl
Sandozol HSI= 10 gpl
Soda Ash= 10 gpl

C) Reactive Series

Receipe

01) Ramazol Turquoise Blue G = 110 gpl
Urea= 100 gpl
Swanic 6L= 10 gpl

02) Sodium Silicate= 250 gpl
Caustic Soda = 10 gpl

Ratio of 01) and 02) = 3:1

D) Ramazol Coffee Brown G

Receipe
01) Coffee Brown G = 100gpl
Urea = 100 gpl
Swanic 6L= 10 gpl

02) Sodium Silicate = 250 gpl
Caustic Soda= 10 gpl

Ratio of 01) and 02) = 3:1

E) Ramazol Parrot Green

Receipe
01) Ramazol Turquoise Blue G = 90 gpl
Ramazol Yellow FG = 40 gpl
Urea= 100 gpl
Swanic 6L= 10 gpl

02) Sodium Silicate = 250 gpl
Caustic Soda = 10 gpl

Ratio of 01) and 02) = 3:1

F) Ramazol Blue

Receipe
01) Ramazol Black B = 70 gpl
Urea = 100 gpl
Swanic 6L = 10 gpl

02) Sodium Silicate = 250 gpl
Caustic Soda = 10 gpl

Ratio of 01) and 02) = 3:1

Friday, 16 May 2008

Notes on Dyeing of sulphur black on Rope Dyeing Range



1. Process of dyeing of sulphur color:

1st Wash tank: mercerisation by taking 22% NaOH ie. 250 gpl
2nd Wash Tank: Hot Wash
3rd Wash Tank: Cold Wash

2. In 1st and 2nd dye bath take sulphur color 6-8% on the weight of the yarn sheet. Temperature 90 deg. cel. The solution contains the following:

1. solubalised sulphur color: 150 gpl
2. Na2S--> reducing agent: It is added to increase its reducing power
3. Caustinc Soda --> 10 gpl--> reducing agent
4. Wetting agent--> 2gpl
5. Antioxident Sulphide ( Glucose paste--> 5gpl). This is added to prevent the oxidation of of Sulphide solution. It will always remain in reduced form
( Alos if the shade is slightly greyish, one can add tiny tinge of sulpher blue--> 20gpl)

in III, IV and V dye bath--> cold wash
in 6th dye bath. We take H2O2(30%)+Acetic Acid(2:1 by weight). H2O2 acts as an oxidising agent. But as it acts on neutral pH (=7) and after cold bath the solution is slightly alkaline, to make it neutral wil add acetic acid. Acs in alkaline pH, oxidising action of H2O2 will be similar to the bleaching action, which may cause tendering in the fabric.

7th and 8th Dye Bath: Cold Wash

Wash Box Number 4: Here washing is done with detergent and soda ash at 60-70 deg.c

5th and 6th Wash Box: Hot Wash

7th wash Box: Here softner is added at 25 gpl. It is cationic softener with pH 4.5 to 6.5. As during oxidation of sulphur, strength is reduced by 10%. On a yarn sulphur is of two types :
1. Free Sulphur
2. Reacted Sulphur.

The free sulphur will react with moisture in the atmosphere to form:
H2O + S --> H2SO4
Which tenders the yarn. Now at acidic pH reaction is much faster. So we add only a small amount of softener (25 gpl) as against that in indigo which is 100gpl.

3rd Point

Over all during sulphur dyeing and storing, the yarn strength is reduced by 15% as compared to Indigo.

4th point

If ball formation takes place of sulphur dyed warp at loom shed, then we can taken in 4th dye bath little Na2S+Caustic to reduce the free sulphur.

Thursday, 15 May 2008

Practical Notes on Rope Dyeing for Indigo Dyed Denim



Practical Considerations in Rope Dyeing for Indigo dyed Denim.

The passage of yarn in rope dyeing is as follows:

Pre-scouring -->hot wash-->cold wash --> Dye baths--> hot wash-->cold wash--> application of softener

lets discuss these processes one by one:

Pre-scouring

1. The objectives of pre-scouring are the removal of wax content from cotton, removal of trapped air from cotton yarn and Making yarn wet

2. This is done at 90 o C

3. We use the following ingredients at pre-scouring stage:

Caustic Soda: Its quantity depends upon the quality of cotton fibres used in the mixing. Generally we take 2-4% of caustic soda. It removes the wax by the action of soapanification.
Wetting agent: It is anionic in nature
Sequestering Agent: Even with the use of water softening, it is very difficult to find the desired softness in water ( about 2-3 ppm) . So we use the agent to make the water soft.

4. Why Trapped Air should be removed. The reason for this can be understood as follows:
In 1 kg of yarn, there is approximately 2 litres of air. 1 litre of air decomposes 1.8 litres of Sodium Hydrosulphide. It will cause uneven dyeing and more consumption of Sodium Hydrosulphide ( hydro).

5. Absorbency of yarn may be checked after scouring.


Hot wash

As some caustic is carried by the yarn after pre-scouring, so hot water is given at 70-800C. If this is not done, this yarn will go into the dye-bath which will change the pH of the dye-bath.

Cold Wash

After hot wash, yarn temperature is more. To bring it back to its room temperature, cold wash is given to it.

INDIGO DYEING

1. Indigo is not a perfect vat color. It may be called a trash vat color. The constant of substantivity for other colors is 30, for indigo it is only 2.7. So there is a need of 5 to 6 dye baths and make the use of multi-dip and multi-nip facility to increase the penetration.
2. The dyeing is done at room temperature as indigo belongs to Ik class of vat dyes, where dyeing is done at room temperature and oxidation is done by air only and not by chemicals. If oxidizing agents are used, they will cause stripping of colors.

3. Indigo is not soluble in water. So it is reduced with Sodium Hydrosulphide. Then caustic soda is added to make sodium salt of vat colors to make it soluble. To reduce 1 kg of Indigo, 700 gms of sodium hydrosulphide is required. However some extra SHS needs to be taken to avoid some decomposition of SHS.

Practically it is prepared in the following sequence

-Take indigo
-Add caustic
-Then reducing agent

4. When caustic is added to indigo, it is an exothermic reaction. It is allowed to cool down, then before sending it to feeder, sodium hydro-sulphide is added. Reducing agent is not added first as it will be decomposed first, so consumption of it will increase. It is also not advisable to take solubalised vat, as offered by some companies due to the following reasons:

a. If it is used after 6 months, there will be a decomposition of sod. Hydrosulphide. It will become partially soluble. Then to make it soluble again, more SHS has to be added.
b. Transportation is difficult
c. Cost is more

5. Feeding System

Rat of flow of yarn is given by

((No of ropes x no of ends x speed of machine)/ count x 1.693 x 1000)

in kg of yarn / minute

So we can determine the rate of feed of indigo. It is very important that replenishment of indigo is there as any variation will result in the change of shade and also if level is more, there is a problem of over-flow.

6. If total capacity of dye bath for example is 15000 litres, then circulation must be 3 times the volume. If it is less then there are 100% chances of getting a lighter shade.

7. Core and ring dyeing effect
This effect is obtained by multidip-multinip facility

8. pH of the Dye bath should be kept in between 10.5-11.5. At this pH , sodium salt of Indigo is mono phenolic form. At this form, the strike rate of dye is very high. So after washing, there will be a better dye effect. At pH 11.5 to 11.7, at this affinity is less, so dye effect will be less prominent.

pH is controlled by the addition of caustic soda.

9. Testing of Hydro

TOTAL HYDRO
We take 10 ml of indio with SHS in 30-35 ml of water. It is set for one minute and shaken. As air will decompose SHS. So vacuum created will fetch the water from above. If 3 ml of water is required, then concentration of hydro is 3 gpl. As a thumb rule, concentration of total hydro should be min. 1.5 gpl.

REDUCED HYDRO

It is the hydro that is used for the reduction of Indigo. It should be around 0.7 ( 1000 kg of Indigo needs 700 kg of hydro to reduce it). For testing we take 10 ml of dye solution and 30 ml of water and 5-6 drops of 40% formaldehyde and shake it for one minute. The water that goes gives the readings of the reduced hydro.

Total Hydro- Reduced Hydro = free hydro

If Total hydro is min. 1.5 gm/lit. then free hydro must be min. 0.5 gms/ litre which acts as buffer

10. Also hydro reduction capacity is measured by mV meter which measures the Redox Potential.

It should be around 760-800

Through the day, the redox potential should be +- 20 mV of the norm. If it is more then the process control is a failure.

Caustic--> It is around 0.4 to 0.5 times the hydro used.

Washing
Rubbing fastness of indigo is very important. On a scale of (1-4), it is 2. Washing is done to improve the rubbing fastness.

Wash at 60 deg.--> Wash at 60 deg.--> Wash at room temperature--> wash with softener

Why Softener:

1. The rope is going to be opened at Long Chain Beamer. It the softener is not used, opening will be hampered.

2. It is generally 1.2% of the weight of the yarn. It is a cationic softener. It is always having pH in the range of 4 to 55. Softening is done at room temperature. If high temperature is used there is always some chance of tendering of yarn.

3. Concept of Buffer pH is given by Virkler USA, they say by addition of this, there is 40% less consumption of Indigo for same shade depth.

4. Metering Consumption

If solution is of 900 litres
10% Indigo-->90 litres
Hydro--> 90*.7 = 63 kg
Caustic--> 63*0.445= 28 kg.

Total Pageviews